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The utilisation of the C4 streams of steamcrackers by converting raffinate II to maleic anhydride was studied. The oxidation reactions were investigated in a laboratory-scale fixed-bed reactor to determine reaction kinetics. The effects of pore diffusional resistance were investigated and explained. A two-dimensional pseudo-homogeneous reactor model was used for the simulation of a production-scale fixed-bed reactor. A flow scheme of the reactor section including a recycle was proposed.
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Partial oxidation of raffinate II and other mixtures of n-butane and n-butenes to maleic anhydride in a fixed-bed reactor, Willi Michael Brandstädter
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- Année de publication
- 2008
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