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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes

A Study of Molecular and Electronic Structure

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Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.

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High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes, Carola Stefanie Vogel

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Année de publication
2016
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Titre
High- and Low-Valent tris-N-Heterocyclic Carbene Iron Complexes
Sous-titre
A Study of Molecular and Electronic Structure
Langue
Anglais
Éditeur
Springer
Publié
2016
Format
souple
Pages
152
ISBN10
3662509059
ISBN13
9783662509050
Description
Carola Vogel’s PhD thesis focuses on the synthesis, and structural and spectroscopic characterization of the first high valent iron nitride complexes. In her interdisciplinary and collaborative research Carola also describes the reactivity studies of a unique iron (V) nitride complex with water. These studies show that quantitative yields of ammonia are given at ambient conditions. High valent iron nitride and oxo species have been proposed as key intermediates in many bio-catalytic transformations, but until now these species have proven exceedingly challenging to isolate and study. Iron complexes in high oxidation states can thus serve as models for iron-containing enzymes to help us understand biological systems or aid our development of more efficient industrial catalysts.